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The
key ingredient is the sugar which has a mystical
characteristic because so many things can
be done with it.
The
confectionery fats (butter) affect the sugar's
final chemical structure and determine the
brittleness, hardness, and flavor and texture
(chewy versus crunchy).
Although
we are not using any gelling agents such as
pectin, agar, starch, or gum - the third ingredient
is usually a thickener or stabilizer in the
gel family. Jellies and lollipops are all
part of this family.
The
final basic ingredient is the protein which
is found in milk. This determines the flow
characteristics and the strength of the candy.
To prevent deformation of a piece of candy,
more milk solids are added. Caramels require
this stability.
During
the manufacture of sugar confections, there
are four primary processes taking place:
1.
Carmelization -
Cane sugar deteriorates in heated conditions
to form a colored breakdown known as carmelization.
2.
Inversion - The
second action is the breakdown of sucrose
into its two simple sugars - dextrose and
fructose. Acids or enzymes accelerate the
process. That is why you add vinegar to some
recipes.
A number of familiar products use inverted
sugars. Fondant centers, fudge, butter confectioners,
chewing gum, jellies, caramels and toffees,
hard creams, high boiled sweets, butterscotch,
marshmallow and soft creams all are results
of this inversion process being careful controlled.
High
levels of inverted sugar, particular fructose,
pick up moisture from the air and the water
is deposited on the surface of the candy.
This water leaches sugar from the candy surface
and you can see a layer-by-layer change in
the candy when water is present.
3.
The third chemical process taking place when
you make candies is called the Maillard
Reaction. Proteins react with
the inverted sugars, adding flavor, texture,
and color. Milk is usually the protein used
and it is an essential part of making caramels,
toffees, and fudge.
The main effect during the production of sugar
confections is the change from ingredients
to a highly saturated syrup.
This
syrup determines the crystalline form the
final product will take. How hot you cook
the syrup and how you stir and agitate it
will make huge differences in the final results.
So will the amounts of ingredients and the
way you cool this hot sugar syrup.
4.
The fourth reaction is the adding of starch
or gel in the process. We know these as pectins,
agars or gums.
The
starch swells in water. The swelling forms
a stress on the sugar crystal structure. Enough
stress will change the basic chemical structure
of the sugar at certain temperature ranges.
When the syrup turns from clear to opaque
the crystalline structure has disappeared
and a jelly or gum has occurred.
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